- carbene complex
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English-Chinese chemistry dictionary (英汉化学大词典). 2013.
carbene complex
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Transition metal carbene complex — A transition metal carbene complex is a organometallic compound featuring a divalent organic ligand. The divalent organic ligand coordinated to the metal center is called a carbene. Carbene complexes for almost all transition metals have been… … Wikipedia
Carbene — In chemistry, a carbene is a highly reactive organic molecule containing a carbon atom with six valence electrons and having the general formula: R1R2C: (two substituents and two electrons). [Organic Chemistry R.T Morrison, R.N Boyd pp 473 478]… … Wikipedia
Persistent carbene — A stable carbene: isolated 1,3 dimesitylimidazol 2 ylidene in a Schlenk flask (stir bar also present). A persistent carbene (also known as stable carbene or Arduengo carbene) is a type of carbene demonstrating particular stability. The best known … Wikipedia
Cyclopentadienyl complex — Zirconocene dichloride, a cyclopentadienyl complex A cyclopentadienyl complex is a metal complex with one or more cyclopentadienyl groups (C5H5−, abbreviated as Cp−). Based on the type of bonding between the metals and the cyclopentadienyl]]… … Wikipedia
Metal carbon dioxide complex — Metal carbon dioxide complexes are coordination complexes that contain carbon dioxide ligands. Aside from the fundamental interest in the coordination chemistry of simple molecules, studies in this field are motivated by the possibility that… … Wikipedia
organometallic compound — ▪ chemical compound Introduction any member of a class of substances containing at least one metal to carbon bond in which the carbon is part of an organic group. Organometallic compounds constitute a very large group of substances that have… … Universalium
Wulff-Dötz reaction — The Wulff Dötz reaction (also known as the Dötz reaction or the benzannulation reaction of the Fischer carbene complexes) is the chemical reaction of an aromatic or vinylic alkoxy pentacarbonyl chromium carbene complex with an alkyne and carbon… … Wikipedia
Olefin metathesis — or transalkylidenation is an organic reaction that entails redistribution of alkylene fragments by the scission of carbon carbon double bonds in olefins (alkenes).[1] Its advantages include the creation of fewer sideproducts and hazardous wastes … Wikipedia
Ring opening metathesis polymerisation — Ring opening metathesis polymerization (ROMP) is a type of olefin metathesis polymerization that produces industrially important products. The driving force of the reaction is relief of ring strain in cyclic olefins (e.g. norbornene or… … Wikipedia
Alkylation — Alkylating agent redirects here. For the class of drugs, see alkylating antineoplastic agent. Alkylation is the transfer of an alkyl group from one molecule to another. The alkyl group may be transferred as an alkyl carbocation, a free radical, a … Wikipedia
Grubbs' catalyst — is a transition metal carbene complex named after the chemist by whom it was first synthesized, Robert H. Grubbs. There are two generations of the catalyst, as shown on the right.Grubbs, R.H. [http://www.wiley… … Wikipedia
